Eugenol synthase
| Eugenol synthase | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifiers | |||||||||
| EC number | 1.1.1.318 | ||||||||
| Databases | |||||||||
| IntEnz | IntEnz view | ||||||||
| BRENDA | BRENDA entry | ||||||||
| ExPASy | NiceZyme view | ||||||||
| KEGG | KEGG entry | ||||||||
| MetaCyc | metabolic pathway | ||||||||
| PRIAM | profile | ||||||||
| PDB structures | RCSB PDB PDBe PDBsum | ||||||||
| |||||||||
Eugenol synthase (EC 1.1.1.318, LtCES1, EGS1, EGS2) is an enzyme with systematic name eugenol:NADP+ oxidoreductase (coniferyl ester reducing).[1][2][3][4][5][6] This enzyme catalyses the following chemical reaction: eugenol + a carboxylate + NADP+ a coniferyl ester + NADPH + H+
The enzyme acts in the reverse direction.
References
- ↑ Koeduka, T.; Fridman, E.; Gang, D.R.; Vassão, D.G.; Jackson, B.L.; Kish, C.M.; Orlova, I.; Spassova, S.M.; Lewis, N.G.; Noel, J.P.; Baiga, T.J.; Dudareva, N.; Pichersky, E. (2006). "Eugenol and isoeugenol, characteristic aromatic constituents of spices, are biosynthesized via reduction of a coniferyl alcohol ester". Proc. Natl. Acad. Sci. USA. 103 (26): 10128–10133. doi:10.1073/pnas.0603732103. PMC 1502517
. PMID 16782809. - ↑ Vassão, D.G.; Kim, S.J.; Milhollan, J.K.; Eichinger, D.; Davin, L.B.; Lewis, N.G. (2007). "A pinoresinol-lariciresinol reductase homologue from the creosote bush (Larrea tridentata) catalyzes the efficient in vitro conversion of p-coumaryl/coniferyl alcohol esters into the allylphenols chavicol/eugenol, but not the propenylphenols p-anol/isoeugenol". Arch. Biochem. Biophys. 465 (1): 209–218. doi:10.1016/j.abb.2007.06.002. PMID 17624297.
- ↑ Louie, G.V.; Baiga, T.J.; Bowman, M.E.; Koeduka, T.; Taylor, J.H.; Spassova, S.M.; Pichersky, E.; Noel, J.P. (2007). "Structure and reaction mechanism of basil eugenol synthase". PLoS ONE. 2 (10): e993–. doi:10.1371/journal.pone.0000993. PMC 1991597. PMID 17912370.
- ↑ Koeduka, T.; Louie, G.V.; Orlova, I.; Kish, C.M.; Ibdah, M.; Wilkerson, C.G.; Bowman, M.E.; Baiga, T.J.; Noel, J.P.; Dudareva, N.; Pichersky, E. (2008). "The multiple phenylpropene synthases in both Clarkia breweri and Petunia hybrida represent two distinct protein lineages". Plant J. 54 (3): 362–374. doi:10.1111/j.1365-313X.2008.03412.x. PMC 2741023. PMID 18208524.
- ↑ Koeduka, T.; Baiga, T.J.; Noel, J.P.; Pichersky, E. (2009). "Biosynthesis of t-anethole in anise: characterization of t-anol/isoeugenol synthase and an O-methyltransferase specific for a C7-C8 propenyl side chain". Plant Physiol. 149 (1): 384–394. doi:10.1104/pp.108.128066. PMC 2613694. PMID 18987218.
- ↑ Gupta A. K.; Schauvinhold I.; Pichersky E.; Schiestl F. P. (2014). "Eugenol synthase genes in floral scent variation in Gymnadenia species". Functional & Integrative Genomics. 14 (4): 779–788. doi:10.1007/s10142-014-0397-9.
External links
- Eugenol synthase at the US National Library of Medicine Medical Subject Headings (MeSH)
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