Diiodobutadiyne
Names | |
---|---|
IUPAC name
1,4-Diiodobuta-1,3-diyne | |
Other names
| |
Identifiers | |
53214-97-4 | |
3D model (Jmol) | Interactive image |
ChemSpider | 126166 |
PubChem | 143018 |
| |
| |
Properties | |
C4I2 | |
Molar mass | 301.85 g·mol−1 |
Appearance | White solid |
Solubility in Hexanes | soluble |
Structure | |
Linear | |
Explosive data | |
Shock sensitivity | Sensitive - may explode if struck |
Related compounds | |
Related compounds |
Diacetylene, PIDA |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
1,4-Diiodobuta-1,3-diyne is a small molecule related to diacetylene. It is used in the creation of the polymer poly(diiododiacetylene) (PIDA) by undergoing 1,4 polymerization.[1] It is light sensitive and explosive if stored out of solution as a dry solid. It will undergo random 1,2 and 1,4 polymerization, as well as decomposition in solution if kept over an extended period of time, having a half life of just about two weeks.[2]
References
- ↑ Sun, A.; Lauher, J.W.; Goroff, N.S. (2006), "Preparation of Poly(Diiododiacetylene), an Ordered Conjugated Polymer of Carbon and Iodine", Science, 312 (5776): 1030–1034, Bibcode:2006Sci...312.1030S, doi:10.1126/science.1124621, PMID 16709780
- ↑ Luo, Liang; Wilhelm, Christopher; Sun, Aiwu; Grey, Clare P.; Lauher, Joseph W.; Goroff, Nancy S. (2008), "Poly(Diiododiacetylene): Preparation, Isolation, and Full Characterization of a Very Simple Poly(diacetylene)", Journal of the American Chemical Society, 103: 7702–7709, doi:10.1021/ja8011403
This article is issued from Wikipedia - version of the 2/12/2016. The text is available under the Creative Commons Attribution/Share Alike but additional terms may apply for the media files.