Cyclopentadienyl anion
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| Identifiers | |||
|---|---|---|---|
| 12127-83-2 | |||
| 3D model (Jmol) | Interactive image | ||
| ChemSpider | 2731064 | ||
| PubChem | 3490527 | ||
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| Properties | |||
| [C5H5]− or Cp− | |||
| Molar mass | 65.09 g/mol | ||
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
| Infobox references | |||
In chemistry, the cyclopentadienyl anion or cyclopentadienide is an aromatic species with a formula of [C5H5]− and abbreviated as Cp−.[1] Its name derives from the molecule cyclopentadiene. Salts of the cyclopentadienyl anion can be stable, e.g., Sodium cyclopentadienide. more complex coordination compounds are known as cyclopentadienyl complexes, such as metallocene
It is a regular pentagonal, planar, cyclic ion; as well, it has 6 π-electrons (4n+2, where n=1), which fulfills Hückel's rule of aromaticity. It can coordinate as a ligand to metal atoms.
The structure shown is a composite of five resonance contributors in which each carbon carries part of the negative charge.
See also
- Tropylium ion
- Cyclopentadienyl
- Cyclopentadienyl cation
- Cyclopentadiene
- Pyrole
- Metallocene
References
- ↑ "Cyclopentadienide". PubChem Compound Database. National Center for Biotechnology Information. Retrieved 14 April 2016.
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