Isotopes of bismuth
Bismuth (Bi) has no stable isotopes, but does have one very long-lived isotope; thus, the relative atomic mass can be given as 208.9803987(16). Although bismuth-209 is now known to be unstable, it has classically been considered to be a "stable" isotope because it has a half-life of over 1.9×1019 years, which is more than a billion (1000 million) times the age of the universe. Besides 209Bi, the most stable bismuth radioisotopes are 210mBi with a half-life of 3.04 million years, 208Bi with a half-life of 368,000 years and 207Bi, with a half-life of 32.9 years, none of which occur in nature. All other isotopes have half-lives under 1 year, most under a day. Of naturally occurring radioisotopes, the most stable is radiogenic 210Bi with a half-life of 5.012 days.
Commercially the radioactive isotope bismuth-213 can be produced by bombarding radium with bremsstrahlung photons from a linear particle accelerator. In 1997 an antibody conjugate with Bi-213, which has a 45-minute half-life, and decays with the emission of an alpha-particle, was used to treat patients with leukemia. This isotope has also been tried in cancer treatment, e.g. in the Targeted Alpha Therapy (TAT) program.[1] Bismuth-213 is also found on the decay chain of uranium-233.
Table
nuclide symbol |
historic name |
Z(p) | N(n) | isotopic mass (u) |
half-life[n 1] | decay mode(s)[2][n 2] |
daughter isotope(s)[n 3] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|---|
excitation energy | ||||||||||
184Bi | 83 | 101 | 184.00112(14)# | 6.6(15) ms | 3+# | |||||
184mBi | 150(100)# keV | 13(2) ms | 10−# | |||||||
185Bi | 83 | 102 | 184.99763(6)# | 2# ms | p | 184Pb | 9/2−# | |||
α (rare) | 181Tl | |||||||||
185mBi | 70(50)# keV | 49(7) µs | α | 181Tl | 1/2+ | |||||
p | 184Pb | |||||||||
186Bi | 83 | 103 | 185.99660(8) | 14.8(7) ms | α | 182Tl | (3+) | |||
β+ (rare) | 186Pb | |||||||||
186mBi | 270(140)# keV | 9.8(4) ms | α | 182Tl | (10−) | |||||
β+ | 186Pb | |||||||||
187Bi | 83 | 104 | 186.993158(16) | 32(3) ms | α (50%) | 183Tl | 9/2−# | |||
β+ (50%) | 187Pb | |||||||||
187m1Bi | 101(20) keV | 320(70) µs | 1/2+# | |||||||
187m2Bi | 252(1) keV | 7(5) µs | (13/2+) | |||||||
188Bi | 83 | 105 | 187.99227(5) | 44(3) ms | α | 184Tl | 3+# | |||
β+ (rare) | 188Pb | |||||||||
188mBi | 210(140)# keV | 220(40) ms | α | 184Tl | (10−) | |||||
β+ (rare) | 188Pb | |||||||||
189Bi | 83 | 106 | 188.98920(6) | 674(11) ms | α (51%) | 185Tl | (9/2−) | |||
β+ (49%) | 189Pb | |||||||||
189m1Bi | 181(6) keV | 5.0(1) ms | (1/2+) | |||||||
189m2Bi | 357(1) keV | 880(50) ns | (13/2+) | |||||||
190Bi | 83 | 107 | 189.9883(2) | 6.3(1) s | α (77%) | 186Tl | (3+) | |||
β+ (30%) | 190Pb | |||||||||
190m1Bi | 420(180) keV | 6.2(1) s | α (70%) | 186Tl | (10−) | |||||
β+ (23%) | 190Pb | |||||||||
190m2Bi | 690(180) keV | >500(100) ns | 7+# | |||||||
191Bi | 83 | 108 | 190.985786(8) | 12.3(3) s | α (60%) | 187Tl | (9/2−) | |||
β+ (40%) | 191Pb | |||||||||
191mBi | 240(4) keV | 124(5) ms | α (75%) | 187Tl | (1/2+) | |||||
β+ (25%) | 191Pb | |||||||||
192Bi | 83 | 109 | 191.98546(4) | 34.6(9) s | β+ (82%) | 192Pb | (3+) | |||
α (18%) | 188Tl | |||||||||
192mBi | 150(30) keV | 39.6(4) s | β+ (90.8%) | 192Pb | (10−) | |||||
α (9.2%) | 188Tl | |||||||||
193Bi | 83 | 110 | 192.98296(1) | 67(3) s | β+ (95%) | 193Pb | (9/2−) | |||
α (5%) | 189Tl | |||||||||
193mBi | 308(7) keV | 3.2(6) s | α (90%) | 189Tl | (1/2+) | |||||
β+ (10%) | 193Pb | |||||||||
194Bi | 83 | 111 | 193.98283(5) | 95(3) s | β+ (99.54%) | 194Pb | (3+) | |||
α (.46%) | 190Tl | |||||||||
194m1Bi | 110(70) keV | 125(2) s | β+ | 194Pb | (6+,7+) | |||||
α (rare) | 190Tl | |||||||||
194m2Bi | 230(90)# keV | 115(4) s | (10−) | |||||||
195Bi | 83 | 112 | 194.980651(6) | 183(4) s | β+ (99.97%) | 195Pb | (9/2−) | |||
α (.03%) | 191Tl | |||||||||
195m1Bi | 399(6) keV | 87(1) s | β+ (67%) | 195Pb | (1/2+) | |||||
α (33%) | 191Tl | |||||||||
195m2Bi | 2311.4+X keV | 750(50) ns | (29/2−) | |||||||
196Bi | 83 | 113 | 195.980667(26) | 5.1(2) min | β+ (99.99%) | 196Pb | (3+) | |||
α (.00115%) | 192Tl | |||||||||
196m1Bi | 166.6(30) keV | 0.6(5) s | IT | 196Bi | (7+) | |||||
β+ | 196Pb | |||||||||
196m2Bi | 270(3) keV | 4.00(5) min | (10−) | |||||||
197Bi | 83 | 114 | 196.978864(9) | 9.33(50) min | β+ (99.99%) | 197Pb | (9/2−) | |||
α (10−4%) | 193Tl | |||||||||
197m1Bi | 690(110) keV | 5.04(16) min | α (55%) | 193Tl | (1/2+) | |||||
β+ (45%) | 197Pb | |||||||||
IT (.3%) | 197Bi | |||||||||
197m2Bi | 2129.3(4) keV | 204(18) ns | (23/2−) | |||||||
197m3Bi | 2360.4(5)+X keV | 263(13) ns | (29/2−) | |||||||
197m4Bi | 2383.1(7)+X keV | 253(39) ns | (29/2−) | |||||||
197m5Bi | 2929.5(5) keV | 209(30) ns | (31/2−) | |||||||
198Bi | 83 | 115 | 197.97921(3) | 10.3(3) min | β+ | 198Pb | (2+,3+) | |||
198m1Bi | 280(40) keV | 11.6(3) min | β+ | 198Pb | (7+) | |||||
198m2Bi | 530(40) keV | 7.7(5) s | 10− | |||||||
199Bi | 83 | 116 | 198.977672(13) | 27(1) min | β+ | 199Pb | 9/2− | |||
199m1Bi | 667(4) keV | 24.70(15) min | β+ (98%) | 199Pb | (1/2+) | |||||
IT (2%) | 199Bi | |||||||||
α (.01%) | 195Tl | |||||||||
199m2Bi | 1947(25) keV | 0.10(3) µs | (25/2+) | |||||||
199m3Bi | ~2547.0 keV | 168(13) ns | 29/2− | |||||||
200Bi | 83 | 117 | 199.978132(26) | 36.4(5) min | β+ | 200Pb | 7+ | |||
200m1Bi | 100(70)# keV | 31(2) min | EC (90%) | 200Pb | (2+) | |||||
IT (10%) | 200Bi | |||||||||
200m2Bi | 428.20(10) keV | 400(50) ms | (10−) | |||||||
201Bi | 83 | 118 | 200.977009(16) | 108(3) min | β+ (99.99%) | 201Pb | 9/2− | |||
α (10−4%) | 197Tl | |||||||||
201m1Bi | 846.34(21) keV | 59.1(6) min | EC (92.9%) | 201Pb | 1/2+ | |||||
IT (6.8%) | 201Bi | |||||||||
α (.3%) | 197Tl | |||||||||
201m2Bi | 1932.2+X keV | 118(28) ns | (25/2+) | |||||||
201m3Bi | 1971.2+X keV | 105(75) ns | (27/2+) | |||||||
201m4Bi | 2739.90(20)+X keV | 124(4) ns | (29/2−) | |||||||
202Bi | 83 | 119 | 201.977742(22) | 1.72(5) h | β+ | 202Pb | 5(+#) | |||
α (10−5%) | 198Tl | |||||||||
202m1Bi | 615(7) keV | 3.04(6) µs | (10#)− | |||||||
202m2Bi | 2607.1(5) keV | 310(50) ns | (17+) | |||||||
203Bi | 83 | 120 | 202.976876(23) | 11.76(5) h | β+ | 203Pb | 9/2− | |||
α (10−5%) | 199Tl | |||||||||
203m1Bi | 1098.14(7) keV | 303(5) ms | IT | 203Bi | 1/2+ | |||||
203m2Bi | 2041.5(6) keV | 194(30) ns | 25/2+ | |||||||
204Bi | 83 | 121 | 203.977813(28) | 11.22(10) h | β+ | 204Pb | 6+ | |||
204m1Bi | 805.5(3) keV | 13.0(1) ms | IT | 204Bi | 10− | |||||
204m2Bi | 2833.4(11) keV | 1.07(3) ms | (17+) | |||||||
205Bi | 83 | 122 | 204.977389(8) | 15.31(4) d | β+ | 205Pb | 9/2− | |||
206Bi | 83 | 123 | 205.978499(8) | 6.243(3) d | β+ | 206Pb | 6(+) | |||
206m1Bi | 59.897(17) keV | 7.7(2) µs | (4+) | |||||||
206m2Bi | 1044.8(5) keV | 890(10) µs | (10−) | |||||||
207Bi | 83 | 124 | 206.9784707(26) | 32.9(14) y | β+ | 207Pb | 9/2− | |||
207mBi | 2101.49(16) keV | 182(6) µs | 21/2+ | |||||||
208Bi | 83 | 125 | 207.9797422(25) | 3.68(4)×105 y | β+ | 208Pb | (5)+ | |||
208mBi | 1571.1(4) keV | 2.58(4) ms | IT | 208Bi | (10)− | |||||
209Bi[n 4][n 5] | 83 | 126 | 208.9803987(16) | 1.9(2)×1019 y[n 6] | α | 205Tl | 9/2− | 1.0000 | ||
210Bi | Radium E | 83 | 127 | 209.9841204(16) | 5.012(5) d | β− | 210Po | 1− | Trace[n 7] | |
α (1.32×10−4%) | 206Tl | |||||||||
210mBi | 271.31(11) keV | 3.04(6)×106 y | α | 206Tl | 9− | |||||
211Bi | Actinium C | 83 | 128 | 210.987269(6) | 2.14(2) min | α (99.72%) | 207Tl | 9/2− | Trace[n 8] | |
β− (.276%) | 211Po | |||||||||
211mBi | 1257(10) keV | 1.4(3) µs | (25/2−) | |||||||
212Bi | Thorium C | 83 | 129 | 211.9912857(21) | 60.55(6) min | β− (64.05%) | 212Po | 1(−) | Trace[n 9] | |
α (35.94%) | 208Tl | |||||||||
β−, α (.014%) | 208Pb | |||||||||
212m1Bi | 250(30) keV | 25.0(2) min | α (67%) | 208Tl | (9−) | |||||
β− (33%) | 212mPo | |||||||||
β−, α (.3%) | 208Pb | |||||||||
212m2Bi | 2200(200)# keV | 7.0(3) min | >15 | |||||||
213Bi[n 10] | 83 | 130 | 212.994385(5) | 45.59(6) min | β− (97.91%) | 213Po | 9/2− | |||
α (2.09%) | 209Tl | |||||||||
214Bi | Radium C | 83 | 131 | 213.998712(12) | 19.9(4) min | β− (99.97%) | 214Po | 1− | Trace[n 7] | |
α (.021%) | 210Tl | |||||||||
β−, α (.003%) | 210Pb | |||||||||
215Bi | 83 | 132 | 215.001770(16) | 7.6(2) min | β− | 215Po | (9/2−) | Trace[n 8] | ||
215mBi | 1347.5(25) keV | 36.4(25) min | (25/2−) | |||||||
216Bi | 83 | 133 | 216.006306(12) | 2.17(5) min | β− | 216Po | 1−# | |||
217Bi | 83 | 134 | 217.00947(21)# | 98.5(8) s | 9/2−# | |||||
218Bi | 83 | 135 | 218.01432(39)# | 33(1) s | 1−# |
- ↑ Bold for isotopes with half-lives longer than the age of the universe (nearly stable)
- ↑ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ↑ Bold for stable isotopes
- ↑ Formerly believed to be final decay product of 4n+1 decay chain
- ↑ Primordial radioisotope, also some is radiogenic from the extinct nuclide 237Np
- ↑ Formerly believed to be the heaviest stable nuclide
- 1 2 Intermediate decay product of 238U
- 1 2 Intermediate decay product of 235U
- ↑ Intermediate decay product of 232Th
- ↑ Used in medicine
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
See also
References
- ↑ Imam, S (2001). "Advancements in cancer therapy with alpha-emitters: a review". International Journal of Radiation Oncology Biology Physics. 51: 271. doi:10.1016/S0360-3016(01)01585-1.
- ↑ "Universal Nuclide Chart". nucleonica. (registration required (help)).
- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005. Check date values in:
|access-date=
(help) - N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
Isotopes of lead | Isotopes of bismuth | Isotopes of polonium |
Table of nuclides |
Isotopes of the chemical elements | |||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 H |
2 He | ||||||||||||||||
3 Li |
4 Be |
5 B |
6 C |
7 N |
8 O |
9 F |
10 Ne | ||||||||||
11 Na |
12 Mg |
13 Al |
14 Si |
15 P |
16 S |
17 Cl |
18 Ar | ||||||||||
19 K |
20 Ca |
21 Sc |
22 Ti |
23 V |
24 Cr |
25 Mn |
26 Fe |
27 Co |
28 Ni |
29 Cu |
30 Zn |
31 Ga |
32 Ge |
33 As |
34 Se |
35 Br |
36 Kr |
37 Rb |
38 Sr |
39 Y |
40 Zr |
41 Nb |
42 Mo |
43 Tc |
44 Ru |
45 Rh |
46 Pd |
47 Ag |
48 Cd |
49 In |
50 Sn |
51 Sb |
52 Te |
53 I |
54 Xe |
55 Cs |
56 Ba |
72 Hf |
73 Ta |
74 W |
75 Re |
76 Os |
77 Ir |
78 Pt |
79 Au |
80 Hg |
81 Tl |
82 Pb |
83 Bi |
84 Po |
85 At |
86 Rn | |
87 Fr |
88 Ra |
104 Rf |
105 Db |
106 Sg |
107 Bh |
108 Hs |
109 Mt |
110 Ds |
111 Rg |
112 Cn |
113 Nh |
114 Fl |
115 Mc |
116 Lv |
117 Ts |
118 Og | |
57 La |
58 Ce |
59 Pr |
60 Nd |
61 Pm |
62 Sm |
63 Eu |
64 Gd |
65 Tb |
66 Dy |
67 Ho |
68 Er |
69 Tm |
70 Yb |
71 Lu | |||
89 Ac |
90 Th |
91 Pa |
92 U |
93 Np |
94 Pu |
95 Am |
96 Cm |
97 Bk |
98 Cf |
99 Es |
100 Fm |
101 Md |
102 No |
103 Lr | |||
|